The influence of Al doping on optical, electrical and structural properties of transparent and conducting SnO2 : Al thin films prepared by spray pyrolysis technique
The influence of increasing Al concentration on the electrical, optical and structural properties of transparent and conducting films has been investigated. The films were deposited on glass substrates at a temperature of 480°C using a hydro-alcoholic solution consisting of and with various Al-doping levels from 0 to 0.53 being spray ratios of : in solution. The effect of changing the aluminum-to-tin spray ratio, [ ]/[ ], from 0 to 0.53 was investigated. The optical properties were studied in the UV/VIS/NIR region. The optical band gap for undoped films lay at 3.9 eV, whereas for high Al -doped films it shifts towards lower energies in the range of 3.9 – 3.61 eV. The results of x-ray diffraction have shown that the deposited films are polycrystalline without any second phases with preferential orientations along the (110), (101), (200) and (211) planes and an average grain size of 25.7 nm. It has been shown that increasing Al doping concentration lowers both the grain size and electrical conductivity of tin oxide significantly.
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The politicization of organization development in Tanzania
This paper is an account to politicization of bureaucracy and its impact on organization development and change in Tanzania. Through a historical approach, it examines the country’s political terrain and the way this has affected the ability of managers of public corporations to be the chief architects in managing changes in the organizations. The theoretical postulate of this paper is that the effectiveness and prosperity of public organizations largely depends on limited political influences and interferences in daily operations of these entities. The general observation that is noted, after a documentary analysis of the then public parastatals, privatized entities and other organizations that continue to be under the control of the government is that soon after independence to the era of the introduction of liberal policies in the country there was excessive politicization of bureaucracy which negatively deprived the managers of their presumed decision making autonomy thereby leading to poor performance of these organizations. It is however noted that since the adoption of liberalization policies positive developments that suggest relative managerial autonomy have taken place. It can however not be asserted that politicization tendencies are over as there are some organizations still suffering from this problem.
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The relationships between cultural intelligence, reading proficiency and vocabulary knowledge of Iranian EFL students
: Now days Culture has become one of the factors that create effects on the performance of the students through four skills and discussing its relationship with one of these skills is a controversial issue. The aim of the present study is to investigate whether there is any significant relationship between intercultural intelligence (known as CQ) awareness and reading proficiency (RP). The participants were 250 Azad University students of English translation with the same level of proficiency but different genders. To this end, the participants first were provided with CQ questionnaire by (Ang et al., 2007) and vocabulary tests which was developed by Paul Nation taken from his website as well as a reading proficiency test developed by Sadeghi and Everatt (submitted). The results of the present paper indicates that there is no significant relationships between cultural intelligence band score and reading proficiency, however a significant relationship among metacognitive factors as one of the four important sub-categories of cultural intelligence was evident. When looking into vocabulary, while a positive significant correlation with CQ band score was found, again similar to the reading proficiency skills a significant relationship between vocabulary knowledge and metacognitive factors was evident. The fact that the results show no correlation between either reading proficiency skills or vocabulary knowledge with cognitive factor represented in the questionnaire needs further research. Key terms: cultural intelligence, culture, reading, proficiency, vocabulary
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The responsivess of inflation to selected monetary policy Instrument in Nigeria-Empirical Analysis
This study examines the responsiveness of inflation to monetary policy in Nigeria. The specific objective was to determine empirically the extent to which monetary policy had helped in achieving general price stability in Nigeria within the chosen scope. Data for the study were obtained from secondary sources. The ordinary least square, Augmented Dickey Fuller (ADF) unit root test, Johansen Co-integration test, as well as parsimonious Error Correction Mechanism method were adopted to analyse the data. The results revealed that the impact of regulatory instrument on inflation was relatively low indicating that monetary policy was not a good predictor of inflation rate in Nigeria. Results also revealed non-stationarity at level form rather stationary after first differencing; and integrated at order one 1(1). Further revelations indicated that a long-run relationship existed among the variables and showed the presence of one co-integrating vector in the model. The study offers some important policy implication: the government should compliment monetary policy with fiscal policy to attain macro-economic objectives, diversifying the economy and encourage local productivity to stabilize prices.
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The surprise of numbers in holy Quran from the Islamic orientation
In this article, we deal with the Holy Quran Miracles from the view point of Numbers. The research is a library one and has focused on the number 19. The Holy Book's depth of meaning and mysteries is something far well-known and has been interpreted and studied from different tenets. This research emphasis on the mathematically numerical relationship between different parts of the Chapters and verses of the wholly Book is novelty and purpose of this research.
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Utilization of photon equation of motion to obtain electromagnetic momentum, time & length in einestein generlazation of special relativity
Special relativity (SR) in the presence of the gravitational field is obtained from the expression of invariant length and a photon equation of motion. Two expressions explain both mass and energy are obtained; one is generalized special relativity (GSR), the other is of Savickas. The (GSR) model is more realistic than Savickas since it is based on the effect of gravity on time which is not recognized by Savickas expression. Moreover (GSR) model predicts pair production phenomena and its equations of motion which are reduced to Newton's second law. Using the equation of motion of the electron in the electromagnetic (E.M) as a simple expression for the total momentum the sum of photon and electron mechanical momentum was found.
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Vibrational spectroscopic and molecular docking studies of 5-Chloro-2-Hydroxy 3-Nitropyridine
In this study, the Fourier Transform infrared (FT-IR) and FT-Raman spectra of 5-chloro-2-Hydroxy-3-Nitro Pyridine (CHNP) have been recorded in the range 4000-400 and 3500-50 cm-1respectively. The quantum mechanical calculations of energies, optimized geometries and fundamental vibrational wave numbers were calculated using the ab initio (HF) and DFT (B3LYP) gradient methods employing 6-311++G (d,p) basis set. The vibrational frequencies which were determined experimentaldata are compared with theoretical calculations. The complete assignments are performed on the basis of total energy distribution (TED) of the vibrational modes. The calculated HOMO-LUMO energy gap reveals that the charge transfer occurs within the molecule. Thermo dynamical properties like entropy, heat capacity, zero-point vibrational energy and Mulliken’s charge analysis have been calculated for CHNP.The most possible interaction is explained using nature bond orbital (NBO) analysis and the potential compound of non-linear optics (NLO) demands the investigation of its structural and bonding features contributing the hyperpolarizability. The optimized geometrical parameters, fundamental vibrational frequencies, IR intensity, Raman activity are calculated using the GAUSSIAN 09W program packages. The molecular docking results were clustered together and represented by the result with the most favourable free energy of binding. Keywords: FTIR; FT-Raman; HF and DFT; HOMO-LUMO; Mulliken charges;Molecular docking
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Water Quality Assessment of River Osun, Osogbo, Nigeria Using HEC-RAS Model
Water is life and every human activity revolves round its availability. Inadequate hydrological data on River Osun has discouraged researchers from modelling water quality across the river. This study modelled water quality across the river using Hydrologic Engineering Centre River Analysis System (HEC-RAS) software. Forty (40) water samples were collected from upstream (70 45' 26", 40 37' 22") (Kajola, Owode), midstream (70 44' 17", 40 33' 20") (Oke-Jetu, Isale-Osun), and downstream (70 45' 06", 40 32' 41") (Gbodofon, Ebunoluwa) sampling stations on River Osun from May 2015 to January 2016. Physical [Temperature and Total Dissolve Solid (TDS)], Chemical [Carbonaceous Oxygen Demand, Dissolved Oxygen, Nitrate-Nitrogen, Nitrite-Nitrogen, and Orthophosphate] and Biological (BOD) tests were carried out on the water samples using standard procedure (APHA, 2005). These parameters were input into HEC-RAS software to simulate water quality on River Osun. Three hundred (300) developed questionnaires on the prevalence of water borne diseases in Osogbo were distributed to households and health workers. Pearson correlation Coefficients (PCC) was used to analyse the data at 5% significance level. Temperature and TDS for rainy and dry season varied from (24.9 - 28.9)0C and (29.0 -339)0C; (90 -110) mg/l; (41.9 - 64.3) mg/l, respectively. The temporal variation of DO, NO3-N, NO2-N and PO43- for rainy and dry seasons parameters varied from (5.2 - 7.6) mg/l and (3.21 - 6.10) mg/l; (0.00 -7.41) mg/l and (9.0 - 19.3); (0.207 - 0.622) and (0.715 - 1.145) mg/l; (3.64 - 5.91) mg/l and (4.04 - 6.21) mg/l, respectively. The BOD values ranged from (0.4 -2 .0) mg/l and (1.93 - 2.96) mg/l, respectively for the rainy and dry seasons. Significance correlation (p< 0.05, 16 df) does occur between the pair of resident with water borne diseases and stations at upstream and midstream of the river in water samples with high pollution sources, there is low correlation (p<0.05 16 and 14 df) between the pair of other stations across the river and residents with water borne diseases. The DO, CBOD, NO3-N, NO2-N, and PO43- output from HEC-RAS for rainy and dry seasons varied from (5.6 -7.4) mg/l and (3.391-5.828) mg/l; (14.81 -15.69) mg/l and (15.87-15.93) mg/l; (0.235 - 5.43827) mg/l and (13.24 -19.1) mg/l; (0.806484 - 1.22) and (0.2085 - 0.4041) mg/l; (3.76-5.16) mg/l and (4.12 - 4.88) mg/l , respectively across the river. The result can be useful to trace the pollution sources and develop water resources management towards achieving Vision 20:2020.
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3-Oxobutanamides in Heterocyclic Synthesis: Synthesis, Reactions and Biological Evaluation of Novel Thiophene, Pyridine, Pyrimidine, 1,2,4-Triazine Derivatives
number of thiophene, pyridine, pyrimidine, and 1,2,4-triazine derivatives were obtained via interaction of 3-Oxo-N-{4-[(2,6-dimethoxypyrimidin-2-yl-amino)sulphonyl]phenyl} butanamide (1) with different reagents. The new synthesized compounds were confirmed by their infrared, mass spectrum, 1H-NMR, 13C-NMR and elemental analyses, and further screened for antimicrobial activity.
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A hybrid method based on optimization algorithm of particle motion (PSO) to predict heart disease
The main cause of morbidity and mortality in modern society is heart disease. Medical diagnosis is important but complex task that must be carefully and effectively. Although considerable progress has been made in the diagnosis and treatment of heart disease, but research must reach the highest accuracy. Access to a large amount of medical data requires powerful tools for analyzing the resulting data to extract useful knowledge. Data mining is an effective analysis tool for discovering hidden relationships and trends in the data. This paper heart disease through data mining algorithm C & R, the algorithm K nearest neighbor algorithm to move the mass of particles (pso) and improved algorithms, k-nearest neighbor algorithm pso investigated. In this study, we improved the effectiveness of these algorithms see for heart disease. Thus we see that data mining can identify or predict high or low risk of heart disease.
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